Wydział Chemii

Synthesis of micrometre-thick oriented 2D covalent organic framework films by a kinetic polymerization pathway, Luca Cusin, Piotr Cieciórski, Samuel Van Gele, Fabian Heck, Simon Krause, Pawel W. Majewski, Bettina V. Lotsch, Wojciech Danowski, Paolo Samorì, Nature Synthesis 2025, 4, 632–641, https://doi.org/10.1038/s44160-025-00741-7

This dataset contains the experimental data used to generate the data-containing panels of Figures 2–5 in the above-mentioned publication.

The dataset contains:

1. Functional-group conversion values for the polymerization of TPB with aldehydes 1–10 (Fig. 2b).
2. Concentration–temperature sol–gel phase-boundary data for TPB-1 (Fig. 2c).
3. SEM source images of the lyophilized solid component of the TPB-1 gel phase (Fig. 2d).
4. Relative amounts of imine, branch-terminating aldehyde and monomer aldehyde groups as a function of TPB-1 concentration (Fig. 2e).
5. Cross-sectional SEM images of the oriented amorphous TPB-1 CAN film (Fig. 3a).
6. Raw 2D GIWAXS detector frames used for the amorphous-film pattern and its in-plane/out-of-plane projections (Fig. 3b,c).
7. Cross-sectional SEM images of the oriented crystalline TPB-1 2D COF film (Fig. 3e).
8. Raw 2D GIWAXS detector frames used for the crystalline-film pattern and its in-plane/out-of-plane projections (Fig. 3f,g).
9. Ex situ SEM images of the TPB-1 coating after 10, 15 and 30 min of drying (Fig. 4a).
10. In situ 2D GIWAXS detector frames of the drying TPB-1 CAN film after 10, 15, 30, 60 and 120 min (Fig. 4b).
11. Frequency-sweep rheology data for the TPB-1 gel at 25 °C (Fig. 4c).
12. SEM images of TPB-1 material obtained under slow and fast solvent-evaporation conditions (Fig. 4d).
13. Raw 2D GIWAXS detector frames for TPB-11 2D COF (Fig. 5a).
14. Raw 2D GIWAXS detector frames for BTA-1 2D COF (Fig. 5b).
15. Raw 2D GIWAXS detector frames for TPPy-1 2D COF (Fig. 5c).
16. Raw 2D GIWAXS detector frames for TPPor-1 2D COF (Fig. 5d).

The dataset is provided in a flat structure — all files are located in a single folder. Each filename contains the figure and panel number where the corresponding data were used.

Raw measurement files are retained whenever available. Numerical CSV tables are additionally supplied for the quantitative plots. Original Origin and MestReNova project files associated with these quantitative panels are retained as source files.

File Types and Formats:

1. '.csv' – numerical data tables corresponding to quantitative figure panels.
2. '.bmp' – raw SEM micrographs.
3. '.gfrm' – raw two-dimensional X-ray detector frame files used for GIWAXS analyses.
4. '.opju' – Origin project files containing original gel-point or rheology source data.
5. '.mnova' – MestReNova project files containing NMR data used for quantitative analysis.

CSV files use a semicolon (';') as the field separator and a comma as the decimal separator.